Bentonite Usages
Much of bentonite's usefulness in the drilling and geotechnical
engineering industry comes from its unique rheological properties.
Relatively small quantities of bentonite suspended in water form
a viscous, shear thinning material. Most often, bentonite suspensions
are also thixotropic, although rare cases of rheopectic behavior
have also been reported. At high enough concentrations (~60 grams
of bentonite per litre of suspension), bentonite suspensions begin
to take on the characteristics of a gel (a material with finite
yield strength).
Bentonite can be used in cement, adhesives, ceramic bodies, cosmetics
and cat litter. Fuller's earth, an ancient dry cleaning substance,
is finely ground bentonite, typically used for purifying transformer
oil. Bentonite, in small percentages, is used as an ingredient in
commercially designed clay bodies and ceramic glazes. Bentonite
clay is also used in pyrotechnics to make end plugs and rocket nozzles,
and can also be used as a therapeutic face pack for the treatment
of acne/oily skin.
The ionic surface of bentonite has a useful property in making
a sticky coating on sand grains. When a small proportion of finely
ground bentonite clay is added to hard sand and wetted, the clay
binds the sand particles into a moldable aggregate known as green
sand used for making molds in sand casting. Some river deltas naturally
deposit just such a blend of such clay silt and sand, creating a
natural source of excellent molding sand that was critical to ancient
metalworking technology. Modern chemical processes to modify the
ionic surface of bentonite greatly intensify this stickiness, resulting
in remarkably dough-like yet strong casting sand mixes that stand
up to molten metal temperatures.
The same effluvial deposition of bentonite clay onto beaches accounts
for the variety of plasticity of sand from place to place for building
sand castles. Beach sand consisting of only silica and shell grains
does not mold well compared to grains coated with bentonite clay.
This is why some beaches are so much better for building sand castles
than others.
The self-stickiness of bentonite allows high-pressure ramming or
pressing of the clay in molds to produce hard, refractory shapes,
such as model rocket nozzles. Indeed, to test whether a particular
brand of cat litter is bentonite, simply ram a sample with a hammer
into a sturdy tube with a close-fitting rod; bentonite will form
a very hard, consolidated plug that is not easily crumbled.
Bentonite also has the interesting property of adsorbing relatively
large amounts of protein molecules from aqueous solutions. It is
therefore uniquely useful in the process of winemaking, where it
is used to remove excessive amounts of protein from white wines.
Were it not for this use of bentonite, many or most white wines
would precipitate undesirable flocculent clouds or hazes upon exposure
to warmer temperatures, as these proteins denature. It also has
the incidental use of inducing more rapid clarification of both
red and white wines.
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